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Stans EEC: effects of photons on Oxygen..

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  • Stans EEC: effects of photons on Oxygen..

    quoted from:
    Auroras: Why oxygen atoms emit different colors at different altitudes
    Q: Why do oxygen atoms emit different colors at different altitudes during an aurora display?

    An aurora taken from the International Space Station, as it orbited earth at about the same altitude as the aurora. Photo courtesy of NASA.

    An aurora taken from the International Space Station, as the ISS orbited earth at about the same altitude as the aurora. From orbit, Pettit reported that flickering auroras appeared to crawl around like giant, green amoebas. Photo courtesy of Don Pettit, NASA.

    During an aurora display, different atoms glow different colors (depending on their electrical state-ionized or neutral-and on the incoming particle's energy) to form vibrant, many-hued rings over Earth. Bombarded nitrogen ions shine blue and neutral nitrogen shines red. Oxygen atoms hit by incoming charged particles 200 miles high glow red, the rarest aurora color. At about 60 miles, glowing oxygen produces the most common color: a brilliant yellow-green.

    An atom glows because the charged particle that hit it transferred kinetic energy to the atom. The atom often dumps the extra energy by emitting light and returns to its normal energy state. It glows like a neon atom inside a neon sign. The red and green oxygen emissions "...come from 'metastable' transitions, which means that once the oxygen atom enters an excited state, it sits there for a period of time before emitting a photon of light and returning to its original state," says Joe Hawkins, director of the Alaska Space Grant Program.

    The excited red-energy state (6300 Angstroms) has a lifetime of about 110 seconds; whereas, the green (5577 Angstroms) has a lifetime of only 0.75 second. These widely discrepant times make a big difference because of collisions with neutral atoms. If a neutral atom bumps into an excited atom, the exited atom can change state before emitting its photon of light. So it doesn't emit light.

    There's fewer atoms up high so they are less likely to collide. At 200 miles up, the exited red-energy state oxygen atoms have the time it takes for them to sit around for 110 seconds and then glow red. Down at 60 miles where oxygen atoms crowd together, however, a neutral atom is likely to hit a red-excited atom in the intervening 110 seconds so it can't glow red. A fast acting green-excited atom is better off. It only needs 0.75 second to emit its green photon and can likely do so without getting bumped by a neutral atom in the meantime. So it glows green.

    That's the main reason. Another reason, says Hawkins, is a playoff between the availability of incoming electron "bullets" and of neutral atom "targets". At high altitude, there are few targets (because the atom density is low) and, at low altitude, few bullets (because of collision higher up). Thus, there is an intermediate altitude in which an optimum number of electron "bullets" and oxygen-atom "targets" exist to create the most excited atoms. That altitude for oxygen is 60 miles.

  • #2
    ozone reaction

    Emission of energy. Electrons, atoms, and molecules normally do not remain in an excited state for very long. They tend to give off their excess energy very quickly and return to their original state. When they do so, they often undergo a chemical change. Since this change was originally made possible by absorbed light energy, it is known as a photochemical change.

    The formation of ozone is just one example of the many kinds of photochemical changes that can occur. When solar energy breaks an oxygen molecule into two parts, one or both of the oxygen atoms formed may be excited. Another way to write the very first equation above is as follows:

    O2 + hν → O* + O

    The excited oxygen atom (O*) then has the excess energy needed to react with a second oxygen molecule to form ozone:

    O* + O2 → O3

    Another way for an excited atom or molecule to lose its energy is to give it off as light. This process is just the reverse of the process by which the atom or molecule first became excited. If the atom or molecule gives off its excess energy almost immediately, the material in which it is contained glows very briefly, a process known as fluorescence. If the excess energy is given off more slowly over a period of time, the process is known as phosphorescence. Both fluorescence and phosphorescence are examples of the general process of light emission by excited materials known as luminescence.

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    • #3
      Notes on Electron energy states...

      Water forms anywhere from 1 to 4 different Hydrogen Bonds.

      Hydrogen covalent bonds are weaker than typical covalent bonds of other compounds.

      Hydrogen Bonds like to connect things in a straight line.

      Atoms usually only absorb radiation in their ground state, but a diatomic molecule (such as O2) can absorb from many different rotational states.

      it takes 13.06 to 13.15 eV for auto ionization of O2

      13.1 eV = a photon at 95 nm wavelength

      535 eV are required to move a ground state electron into the second orbit of oxygen.

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